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Beilstein J. Org. Chem. 2013, 9, 925–933, doi:10.3762/bjoc.9.106
Graphical Abstract
Figure 1: Localized singlet diradicals.
Scheme 1: Alkoxy group effect on the lifetime of π-single-bonded species DR.
Scheme 2: Generation of singlet diradicals DRc–g and their reactivity in the photochemical denitrogenation of ...
Scheme 3: Synthesis of azoalkanes AZc–f and AZg.
Figure 2: (a) Absorption spectrum of the singlet diradical DRe in a MTHF matrix at 80 K; (b) transient absorp...